Benzoic acid–2,9-dimethylphenanthroline (1/1)
نویسندگان
چکیده
The constituents of the title 1:1 co-crystal, C(7)H(6)O(2)·C(14)H(12)N(2), are connected into dimeric aggregates by a bifurcated O-H⋯N hydrogen bond; the hydroxyl-H atom is hydrogen bonded to the two N atoms of the 2,9-dimethyl-phenanthroline. The hydrogen-bonded residues are almost orthogonal to each other [dihedral angle = 78.56 (7) °]. In the crystal packing, the aggregates are assembled into layers in the bc plane by π⋯π inter-actions [ring centroid⋯ring centroid distance = 3.5577 (16) Å] involving the pyridyl rings, and C-H⋯π contacts involving the phenanthroline-H atom and the phenyl ring of the acid.
منابع مشابه
2,2′-(Disulfanediyl)dibenzoic acid–2,9-dimethylphenanthroline–tetrahydrofuran (1/2/1)
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